キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 2005/05
形態種別 学術雑誌
査読 査読あり
標題 Efficient synthesis of [2]- and higher order rotaxanes via the transition metal-catalyzed hydrosilylation of alkyne
執筆形態 共著
掲載誌名 Tetrahedron Lett.
巻・号・頁 46(22),pp.3851-3853
著者・共著者 Hisahiro Sasabe, Nobuhiro Kihara, Kazuhiko Mizuno, Akiya Ogawa, Toshikazu Takata
概要 A novel end-capping method of pseudorotaxanes via the hydrosilylation of the alkyne of the axle terminal was developed. RuHCl(CO)(PPh3)3 and RhCl(CO)(PPh3)3 complexes catalyzed the hydrosilylation reactions of the alkyne moiety of several pseudorotaxanes at ambient temp. to give the corresponding [2]- and higher order rotaxanes in high yields with excellent regio- and stereoselectivity.
DOI 10.1016/j.tetlet.2005.03.186
ISSN 0040-4039