研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2006/02
形態種別	学術雑誌
査読	査読あり
標題	Synthesis of [60]fullerene-functionalized rotaxanes
執筆形態	共著
掲載誌名	Tetrahedron
巻・号・頁	62(9),pp.1988-1997
著者・共著者	Hisahiro Sasabe, Kei-ichiro Ikeshita, G. A. Rajkumar, Nobuhiro Watanabe, Nobuhiro Kihara, Yoshio Furusho, Kazuhiko Mizuno, Akiya Ogawa, Toshikazu Takata
概要	Synthesis of [60]fullerene (C60)-functionalized rotaxanes via Diels-Alder reactions with C60 is described. Diels-Alder reaction of C60 and sulfolene moiety as masked diene attached on the wheels of rotaxanes results in high yields of C60 incorporation. Rotaxanes are prepd. by tin-catalyzed urethane-forming end-capping reaction with isocyanate of pseudorotaxane having the wheel carrying C60 functionality as introduced by the Diels-Alder reaction. The Diels-Alder reaction was accomplished as end-capping reaction between C60 and pseudorotaxane bearing sultine moiety as masked diene on the axle terminal. A variety of C60-contg. [2]rotaxanes was prepd. in moderate to good yields by these Diels-Alder protocols.
DOI	10.1016/j.tet.2005.09.149
ISSN	0040-4020