キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 2006/02
形態種別 学術雑誌
査読 査読あり
標題 Rotaxane synthesized by end-capping via hydroruthenation of axle terminal acetylene and its derivation to η3-allylruthenium complex-containing rotaxane
執筆形態 共著
掲載誌名 Chem. Lett.
巻・号・頁 35(2),pp.212-213
著者・共著者 Hisahiro Sasabe, Nobuhiro Kihara, Kazuhiko Mizuno, Akiya Ogawa, Toshikazu Takata
概要 The hydroruthenation of pseudorotaxane I·DB24C8 having an alkyne moiety at the axle terminal with RuHCl(CO)(PPh3)3 gave [2]rotaxane with an alkenylruthenium complex moiety in a good yield. The carbometalation of allenes with [2]rotaxane resulted in the formation of the corresponding [2]rotaxanes with η3-allylruthenium complex moieties in good yields.
DOI 10.1246/cl.2006.212
ISSN 0366-7022