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キハラ ノブヒロ
Kihara Nobuhiro 木原 伸浩 所属 神奈川大学 理学部 理学科 神奈川大学大学院 理学研究科 理学専攻（化学領域） 職種 教授 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2006/06 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | Transition-metal-catalyzed carbonylation of allenes with carbon monoxide and thiols |
| 執筆形態 | 共著 |
| 掲載誌名 | Tetrahedron |
| 巻・号・頁 | 62(26),pp.6355-6360 |
| 著者・共著者 | Minako Kajitani, Ikuyo Kamiya, Akihiro Nomoto, Nobuhiro Kihara, Akiya Ogawa |
| 概要 | Unsatd. thioesters such as RCH2C(:CH2)COSR1 and (E)-RCH:CHCH2COSR1 (R = cyclohexyl, BuCH2CH2, PhCH2; R1 = cyclohexyl) are prepd. by carbonylative thiolation of allenes such as RCH:C:CH2 (R = cyclohexyl, BuCH2CH2, PhCH2) with carbon monoxide and cyclohexanethiol in the presence of tetrakis(triphenylphosphine)platinum. 1-Cyclohexyl-1,2-propadiene and carbon monoxide react in the presence of either Wilkinson's catalyst or carbonylhydridotris(triphenylphosphine)rhodium to give a copolymer without incorporation of cyclohexanethiol. Other platinum, palladium, or cobalt complexes are either less effective or ineffective as catalysts for the carbonylative thiolation of 1-cyclohexyl-1,2-propadiene. |
| DOI | 10.1016/j.tet.2006.04.039 |
| ISSN | 0040-4020 |
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