キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 2007/01
形態種別 学術雑誌
査読 査読あり
標題 Catalytic Asymmetric Synthesis and Optical Resolution of Planar Chiral Rotaxane
執筆形態 共著
掲載誌名 Chem. Lett.
巻・号・頁 36(1),pp.162-163
著者・共著者 Yoshimasa Makita, Nobuhiro Kihara, Naohisa Nakakoji, Toshikazu Takata, Shinji Inagaki, Chiyo Yamamoto, Yoshio Okamoto
概要 Planar chiral rotaxanes were synthesized from crown ether and secondary ammonium salt via trialkylphosphine-catalyzed acylative end-capping. Their optical resoln. was achieved by chiral HPLC after acylative neutralization of the ammonium group. When optically active phosphine (Me3CPMeCH2)2 was used as the chiral acylation catalyst, optically active rotaxane (4.4% ee) was obtained.
DOI 10.1246/cl.2007.162
ISSN 0366-7022