キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 理学科
    神奈川大学大学院  理学研究科 理学専攻(化学領域)
   職種   教授
言語種別 英語
発行・発表の年月 2014
形態種別 学術雑誌
査読 査読あり
標題 Directed one-pot syntheses of crown ether wheel-containing main chain-type polyrotaxanes with controlled rotaxanation ratios
執筆形態 共著
掲載誌名 Chem. Commun.
巻・号・頁 50(97),pp.15341-15344
著者・共著者 Kazuko Nakazono, Tomonori Ishino, Tomoyuki Takashima, Daisaku Saeki, Daisuke Natsui, Nobuhiro Kihara, Toshikazu Takata
概要 The directed synthesis of main chain-type polyrotaxanes possessing crown ether wheels was successfully achieved through two methods, A and B. Method A involved the direct wheel threading of poly(sec-ammonium salt) followed by end-capping with a bulky group, while method B utilized polyaddn. of a pseudo[2]rotaxane monomer to facilitate the control of the structure, i.e. the rotaxanation ratio.
DOI 10.1039/C4CC06943A
ISSN 1359-7345