キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 日本語
発行・発表の年月 2001/03
形態種別 学術雑誌
査読 査読あり
招待 招待あり
標題 水素結合を利用したインターロックト分子の高効率合成:ロタキサン、カテナン合成の最近の進歩
執筆形態 共著
掲載誌名 有機合成化学協会誌
巻・号・頁 59(3),206-218頁
著者・共著者 木原 伸浩、高田 十志和
概要 A review with 94 refs. This review summarizes the efficient synthesis of interlocked compds. based on hydrogen-bonding interaction. Various synthetic methods including threading followed by end-capping, clipping, slipping, entering, and polyslipping are discussed. Synthesis under thermodn. control is also discussed. Various amide-based catenanes and rotaxanes have been synthesized using the template effect based on amide-amide H bonding or anion recognition by macrolactam. The strong H bonding between cucurbituril and ammonium salts allowed to prep. various structures of catenanes, rotaxanes, and polyrotaxanes. Further, secondary ammonium salts can be captured into the rings of crown ethers consisting ≥24 ring member to give pseudorotaxanes. A wide variety of end-capping techniques have been developed to give crown ether-based rotaxanes. Control of intramol. H bonding interaction in the interlocked compds. are briefly discussed.
DOI 10.5059/yukigoseikyokaishi.59.206
ISSN 0037-9980