キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 1994/01
形態種別 学術雑誌
査読 査読あり
標題 Cationic Polymerization of 2-Isopropenyl-4-methylene-1,3-dioxolane in the Presence of Nucleophilic Compound
執筆形態 共著
掲載誌名 J. Polym. Sci. Part A: Polym. Chem.
巻・号・頁 32(1),pp.199-201
著者・共著者 Jaekyeung Park, Nobuhiro Kihara, Masahiro Kobayashi, and Takeshi Endo
概要 The title compd. (I) was polymd. by selectively opening the ring at the enolic site to give linear sol. polyether-polyketone at ambient temp. using CF3SO3H in the presence of PhSMe as the nucleophile. In the absence of PhSMe, I gave only crosslinked polymer when polymd. by CF3SO3H or CH3SO3H. CH3SO3H did not polymerize I in the presence of PhSMe at ambient temp., although it was an effective catalyst for producing linear polymer when used alone at -78°.
DOI 10.1002/pola.1994.080320124
ISSN 0887-624X