キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 1994/10
形態種別 学術雑誌
査読 査読あり
標題 Self-Catalyzed Carbon Dioxide-Incorporation System. The Reaction of Copolymer Bearing Oxirane and Quarternary Ammonium Group and Carbon Dioxide
執筆形態 共著
掲載誌名 Macromolecules
巻・号・頁 27(22),pp.6239-6244
著者・共著者 Nobuhiro Kihara and Takeshi Endo
概要 Copolymers of glycidyl methacrylate (GMA) and N-benzyl-N-[2-(methacryloyloxy)ethyl]-N,N-dimethylammonium bromide (I) were synthesized by radical copolymn. in MeCN using AIBN as an initiator. When the copolymers were reacted with CO2 at 100-130 °, 75-86% of the epoxide groups were converted to the five-membered cyclic carbonate moiety by self-catalyzation. A crosslinked copolymer was synthesized by radical copolymn. of GMA, I, and divinylbenzene (93:5:2) and exposed to CO2 to attain 61% incorporation at 140 ° for 500 min.
DOI 10.1021/ma00100a002
ISSN 0024-9297