キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 日本語
発行・発表の年月 1996/07
形態種別 学術雑誌
査読 査読あり
招待 招待あり
標題 ポリグリシジルメタクリラートと二酸化炭素の固相高分子反応による5員環カーボナート構造を有する反応性高分子の合成
執筆形態 共著
掲載誌名 日本接着学会誌
巻・号・頁 32(7),248-255頁
著者・共著者 遠藤 剛、木原 伸浩
概要 A film of poly(glycidyl methacrylate) (PGMA) in which an alkali metal halide was dissolved homogeneously was exposed to carbon dioxide. The film rapidly absorbed carbon dioxide to afford a corresponding polymer bearing 5-membered cyclic carbonate group (PDOMA). Although this solid state-polymer reaction proceeded along with a corresponding polymer reaction in soln., side reactions including crosslinking were accompanied. Since these side reactions were accelerated by using a more active catalyst, the highest incorporation of carbon dioxide was achieved by using a moderately active catalyst. It can be concluded that this solid-state polymer reaction was characterized by 2 factors: crosslinking by the reaction of alkoxide and epoxide and the acceleration of bi-mol. reactions.
ISSN 0916-4812