研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	日本語
発行・発表の年月	1996/07
形態種別	学術雑誌
査読	査読あり
招待論文	招待あり
標題	ポリグリシジルメタクリラートと二酸化炭素の固相高分子反応による５員環カーボナート構造を有する反応性高分子の合成
執筆形態	共著
掲載誌名	日本接着学会誌
巻・号・頁	32(7),248-255頁
著者・共著者	遠藤　剛、木原　伸浩
概要	A film of poly(glycidyl methacrylate) (PGMA) in which an alkali metal halide was dissolved homogeneously was exposed to carbon dioxide. The film rapidly absorbed carbon dioxide to afford a corresponding polymer bearing 5-membered cyclic carbonate group (PDOMA). Although this solid state-polymer reaction proceeded along with a corresponding polymer reaction in soln., side reactions including crosslinking were accompanied. Since these side reactions were accelerated by using a more active catalyst, the highest incorporation of carbon dioxide was achieved by using a moderately active catalyst. It can be concluded that this solid-state polymer reaction was characterized by 2 factors: crosslinking by the reaction of alkoxide and epoxide and the acceleration of bi-mol. reactions.
ISSN	0916-4812