キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 1998/01
形態種別 学術雑誌
査読 査読あり
標題 A Novel One-Pot Oxidation Polymerization of Dithiols Obtained from Bifunctional Five-Membered Cyclic Dithiocarbonates with Amines
執筆形態 共著
掲載誌名 J. Polym. Sci., Part A: Polym. Chem.
巻・号・頁 36(1),pp.79-84
著者・共著者 Wonmun Choi, Fumio Sanda, Nobuhiro Kihara, and Takeshi Endo
概要 One-pot oxidn. polymn. of dithiols of bifunctional five-membered cyclic dithiocarbonates with two equiv. of amines, was carried out. The dithiol monomers were synthesized by the reactions of bisphenol A diglycidyl ether and neopentyl glycol diglycidyl ether with carbon disulfide, resp. Polydisulfides with av. mol. wt. Mns 4600-20,200 were obtained quant. from the bisphenol A diglycidyl ether dithiol prepd. in situ by reaction with benzylamine, n-butylamine, or piperidine, followed by oxidn. polymn. On the other hand, dithiols obtained from neopentyl glycol diglycidyl ether with benzylamine, afforded cyclic disulfides and the polysulfide under similar conditions.
DOI 10.1002/(SICI)1099-0518(19980115)36:1<79::AID-POLA11>3.0.CO;2-A
ISSN 0887-624X