研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	1999/10
形態種別	学術雑誌
査読	査読あり
標題	High Yielding and Practical Synthesis of Rotaxanes by Acylative End-Capping Catalyzed by Tributylphosphine
執筆形態	共著
掲載誌名	Chem. Lett.
巻・号・頁	(10),pp.1015-1016
著者・共著者	Hiroaki Kawasaki, Nobuhiro Kihara, and Toshikazu Takata
概要	A pseudorotaxane was prepd. from dibenzo-24-crown-8 and a dibenzylammonium salt possessing dimethylphenyl and hydroxy groups at the termini. Acylation of the pseudorotaxane by 3,5-dimethylbenzoic anhydride in the presence of tributylphosphine afforded the corresponding rotaxane in 90% yield. Various rotaxanes were readily synthesized in excellent yields by this method.
DOI	10.1246/cl.1999.1015
ISSN	0366-7022