キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 2000/01
形態種別 学術雑誌
査読 査読あり
標題 "Unlock-Lock" Approach to [2] and [3]Rotaxanes: Entering of a Ring through Disulfide Linkage That is Unlocked by Thiol "Key"
執筆形態 共著
掲載誌名 Chem. Lett.
巻・号・頁 (1),pp.18-19
著者・共著者 Yoshio Furusho, Toshihide Hasegawa, Akiyoshi Tsuboi, Nobuhiro Kihara, and Toshikazu Takata
概要 Both [2] and [3] rotaxanes were prepd. from dibenzo-24-crown-8 and [3,5-(Me3C)2C6H3CH2NHCH2CH2S]2.2HPF6 by treatment with PhSH to cleave the disulfide. During the reversible cleavage of the disulfide linkage, catalyzed by the benzenethiol, the disulfide linkage entered the crown ether to afford the rotaxanes.
DOI 10.1246/cl.2000.18
ISSN 0366-7022