キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 2001/02
形態種別 学術雑誌
査読 査読あり
標題 Synthesis, Structure, and Host Ability of Macrocycles Based on the Structural Diversity of 1,3-Diene
執筆形態 共著
掲載誌名 Tetrahedron Lett.
巻・号・頁 42(9),pp.1699-1702
著者・共著者 Hiroshi Yamaguchi, Saburo Nakanishi, Nobuhiro Kihara, and Toshikazu Takata
概要 Macrocycles consisting of both a 1,3-diene unit and a polyether linkage were prepd. by the reaction of muconic chloride with diols contg. a polyether linkage. The 1,3-diene moiety was complexed by Fe(CO)3 to furnish macrocycles bearing a (η4-diene)Fe(CO)3 moiety. The structures of the macrocycles were detd. by NMR and IR, and by x-ray structural anal. The macrocycles formed complexes with some ammonium salts and their assocn. consts. varied according to whether the structure of the 1,3-diene moiety was complexed or uncomplexed. Ring-size effects of the macrocycles on the assocn. consts. were also studied.
DOI 10.1016/S0040-4039(00)02328-5
ISSN 0040-4039