キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 2003/02
形態種別 学術雑誌
標題 Photoinduced Intrarotaxane Electron Transfer between Zinc Porphyrin and [60]Fullerene in Benzonitrile
執筆形態 共著
掲載誌名 Angew. Chem. Int. Ed.
巻・号・頁 42(6),pp.681-683
著者・共著者 Nobuhiro Watanabe, Nobuhiro Kihara, Yoshio Furusho, Toshikazu Takata, Yasuyuki Araki, and Osamu Ito
概要 A zinc porphyrin rotaxane was prepd. with consists of a C60 fullerene functionalized macrocyclic ring encircling an isophthalamide deriv. linked to two zinc porphyrin stoppers. The photophys. properties of the rotaxane were detd. based upon steady-state absorption and emission spectra and transient absorption spectrum. The photoinduced intrarotaxane electron transfer is described. The photophys. properties of the fullerene functionalized rotaxane are compared with those of an analogous rotaxane without the fullerene moiety.
DOI 10.1002/anie.200390188
ISSN 1433-7851