キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 2004/05
形態種別 学術雑誌
査読 査読あり
標題 Redox Behavior of Ferrocene-Containing Rotaxane: Transposition of the Rotaxane Wheel by Redox Reaction of a Ferrocene Moiety Tethered at the End of the Axle
執筆形態 共著
掲載誌名 Org. Lett.
巻・号・頁 6(11),pp.1693-1696
著者・共著者 Nobuhiro Kihara, Makiko Hashimoto, and Toshikazu Takata
概要 A rotaxane with a ferrocene moiety at the axle terminus was prepared. The redox potential of the ferrocene moiety decreased by ca. 80 mV when the rotaxane had a crown ether wheel capable of moving on the axle. Thus, the stabilization of the oxidized state of the ferrocene moiety is assumed to accompany the transposition of the wheel component on the axle toward the ferrocene moiety.
DOI 10.1021/ol049817d
ISSN 1523-7060