キハラ ノブヒロ   Kihara Nobuhiro
  木原 伸浩
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 英語
発行・発表の年月 2004/09
形態種別 学術雑誌
査読 査読あり
標題 Bridged Polycatenane
執筆形態 共著
掲載誌名 Macromolecules
巻・号・頁 37(18),pp.6663-6666
著者・共著者 Nobuhiro Watanabe, Yoshihiro Ikari, Nobuhiro Kihara, and Toshikazu Takata
概要 Catenane monomer possessing both diene and dienophile moieties was synthesized by macrocyclization of triethylene glycol bis(3-chlorocarbonylphenyl) ether with bis(3-aminophenyl) butenedioate in the presence of sulfolene-contg. cyclic ester-amide. The Diels-Alder polymn. of the synthesized monomer was carried out by heating in 1,2-dichlorobenzene or without solvent at temp. 140°. Polymn. involves the initial decompn. of the sulfolene moiety followed by the Diels-Alder reaction.
DOI 10.1021/ma048782u
ISSN 0024-9297