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ホリ ヒサオ
Hori Hisao 堀 久男 所属 神奈川大学 理学部 理学科 神奈川大学大学院 理学研究科 理学専攻（化学領域） 職種 教授 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2018/10 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | Oxidative removal of dibenzothiophene and related sulfur compounds from
fuel oils under pressurized oxygen at room temperature with hydrogen peroxide and a phosphorus-free catalyst: sodium decatungstate |
| 執筆形態 | 共著 |
| 掲載誌名 | Fuel Processing Technology |
| 掲載区分 | 国外 |
| 出版社・発行元 | Elsevier |
| 巻・号・頁 | 179,pp.175-183 |
| 著者・共著者 | Hisao Hori, Keisuke Ogi, Yuya Fujita, Yuta Yasuda, Eri Nagashima, Yusuke Matsuki, Kenji Nomiya |
| 概要 | We investigated the removal of dibenzothiophene (DBT) and related compounds, 4-methyldibenzothiophene (4-MeDBT), 4,6-dimethyldibenzothiophene (4,6-DMeDBT), 2,8-dimethyldibenzothiophene (2,8-DMeDBT), and 1-benzothiophene (1-BT) from several oil media at room temperature under pressurized O2 (0.6 MPa) by means of
a three-phase reaction system consisting of the oil phase, an aqueous phase containing the phosphorus-free polyoxotungstate catalyst Na4W10O32·8H2O, H2O2, and tetraoctylammonium bromide, and the gas phase. Under conditions in which the initial DBT concentration in octane was 10.1 mM, the desulfurization ratio reached 87% after reaction for 6.5 h. Prolonged reaction time to 18 h resulted in 92% desulfurization. The desulfurization of octane decreased in the order 2,8-DMeDBT~DBT > 4-MeDBT>1-BT~4,6-DMeDBT. Light oil and kerosene could also be desulfurized efficiently: after reaction for 6.5 h, the desulfurization ratios reached 77 and 78% for light oil and kerosene, respectively. |
| DOI | 10.1016/j.fuproc.2018.07.003 |
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