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キハラ ノブヒロ
Kihara Nobuhiro 木原 伸浩 所属 神奈川大学 理学部 理学科 神奈川大学大学院 理学研究科 理学専攻（化学領域） 職種 教授 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2006 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | Photoinduced electron transfer processes in three component rotaxanes with porphyrins, [60]fullerene and triphenylamine |
| 執筆形態 | 共著 |
| 掲載誌名 | J. Porphyrins Phthalocyanines |
| 巻・号・頁 | 10(12),pp.1346-1359 |
| 著者・共著者 | Hisahiro Sasabe, Yoshio Furusho, Atula S. D. Sandanayaka, Yasuyuki Araki, Nobuhiro Kihara, Kazuhiko Mizuno, Akiya Ogawa, Toshikazu Takata, Osamu Ito |
| 概要 | Electron transfer processes were studied for novel mech. linked triad [2]rotaxanes, which contain a porphyrin (MP) unit as a pendant and [60]fullerene (C60) and triphenylamine (TPA) moieties as stopper groups at the axle ends (abbreviated as (MP;C60-TPA)rot+ with MP = H2P or ZnP). The charge sepn. took place mainly via (1MP*;C60-TPA)rot+ and (MP;1C60*-TPA)rot+ in polar solvents. Within the charge-sepd. states of the triad (MP;C60-TPA)rot+, hole-shift and/or back electron transfer took place competitively. The lifetime of the charge sepn. state of (ZnP;C60-TPA)rot+ was similar to that of dyad (C60-TPA)rot+ (140 ns in dimethylformamide), whereas that of (H2P;C60-TPA)rot+ was as long as 230 ns, suggesting two final charge sepn. states such as (MP;C60·--TPA·+)rot+ and (MP·+;C60·--TPA)rot+ depending on the kind of porphyrin. |
| DOI | 10.1142/S1088424606000727 |
| ISSN | 1088-4246 |
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