研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2007/04
形態種別	学術雑誌
査読	査読あり
標題	Solvent-Free Synthesis of Pseudopolyrotaxane and Polyrotaxane: Efficient Threading Complexation of a Cyclodextrin Wheel and a Linear Polymer Axle to Yield Pseudopolyrotaxane and Its Fixation to Polyrotaxane by the Direct Grinding of a Solid Mixture
執筆形態	共著
掲載誌名	J. Polym. Sci., Part A: Polym. Chem.
巻・号・頁	45(8),pp.1571-1574
著者・共著者	Runtao Liu, Takeshi Maeda, Nobuhiro Kihara, Akira Harada, Toshikazu Takata
概要	Thus, we have presented a practical solvent-free synthesis of O-trimethyl-α-cyclodextrin-poly(ethylene glycol) pseudopolyrotaxane and its fixation to polyrotaxane with 4-tritylphenyl isocyanate (the evidence for the formation of the pseudopolyrotaxane), both of which are accomplished by the simple grinding of a solid mixt. This work provides a general protocol for the solvent-free synthesis of interlocked compds. The reason that the pseudopolyrotaxane formation is tremendously accelerated in such a heterogeneous system by grinding might be attributed to the effective and intimate solid-solid contact under a microenvironment generated by press grinding, whereas the occurrence of a mechanochem. reaction in a solid-state reaction is known.
DOI	10.1002/pola.21913
ISSN	0887-624X