研究者情報 | 神奈川大学

イワクラ　イズミ Iwakura Izumi 岩倉　いずみ所属神奈川大学化学生命学部応用化学科神奈川大学大学院工学研究科工学専攻（応用化学領域）職種教授
言語種別	英語
発行・発表の年月	2014/10
形態種別	学術雑誌
査読	査読あり
標題	DBU-Promoted regioselective HBr-elimination of vicinal dibromides: Effects of the adjacent oxygen and/or other heterofunctional groups.
執筆形態	共著
掲載誌名	Tetrahedron
掲載区分	国外
出版社・発行元	ELSEVIER
巻・号・頁	70(43),pp.8004-8009
著者・共著者	Noriki Kutsumura, Shohei Toguchi, Masatoshi Iijima, Osamu Tanaka, Izumi Iwakura, Takao Saito
概要	DBU-promoted HBr-eliminations of a variety of vicinal dibromides having an adjacent heteroatom (F, O, or N) under mild basic conditions and relevant theoretical calculations were carried out. These HBr-eliminations proceeded more or less regioselectively, and all associated calculation results agreed with the experimental facts. This work suggests that the HBr-elimination selectivity is an effect of the electronegativity of the neighboring heteroatoms themselves rather than the electron-withdrawing effects of the entire heterofunctional group.
DOI	https://doi.org/10.1016/j.tet.2014.08.041
researchmap用URL	https://www.sciencedirect.com/science/article/pii/S0040402014012253