研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2012/10
形態種別	学術雑誌
査読	査読あり
標題	Oxidative Coupling Polymerization of Bishydrazide for the Synthesis of Poly(diacylhydrazine): Oxidative Preparation of Oxidatively Degradable Polymer
執筆形態	共著
掲載誌名	J. Polym. Sci. Part A: Polym. Chem.
巻・号・頁	50(20),pp.4230-4238
著者・共著者	Kentaro Nagashima, Nobuhiro Kihara, Yusuke Iino
概要	The oxidative coupling polymerization of bishydrazide is successfully performed to form poly(diacylhydrazine) (PDAH), which is an oxidatively degradable polymer. Oxone is an effective oxidant, and a mixture of an aprotic polar solvent, water, and acetonitrile or N,N-dimethylacetamide is necessary as the solvent. On treatment of PDAH with sodium hypochlorite solution or hydrogen peroxide, the PDAH is rapidly oxidized and degraded to the corresponding dicarboxylic acid. When hydrogen peroxide is used as the oxidant, the addition of acetonitrile and potassium carbonate is necessary for effective degradation. PDAH exhibits high thermal stability in air and a high Tg value. No oxidation is observed in air. Thus, PDAH is an oxidatively degradable high-performance polymer that is stable toward oxygen.
DOI	10.1002/pola.26225
ISSN	0887-624X