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キハラ ノブヒロ
Kihara Nobuhiro 木原 伸浩 所属 神奈川大学 理学部 理学科 神奈川大学大学院 理学研究科 理学専攻(化学領域) 職種 教授 |
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言語種別 | 英語 |
発行・発表の年月 | 2014 |
形態種別 | 学術雑誌 |
査読 | 査読あり |
標題 | Directed one-pot syntheses of crown ether wheel-containing main chain-type polyrotaxanes with controlled rotaxanation ratios |
執筆形態 | 共著 |
掲載誌名 | Chem. Commun. |
巻・号・頁 | 50(97),pp.15341-15344 |
著者・共著者 | Kazuko Nakazono, Tomonori Ishino, Tomoyuki Takashima, Daisaku Saeki, Daisuke Natsui, Nobuhiro Kihara, Toshikazu Takata |
概要 | The directed synthesis of main chain-type polyrotaxanes possessing crown ether wheels was successfully achieved through two methods, A and B. Method A involved the direct wheel threading of poly(sec-ammonium salt) followed by end-capping with a bulky group, while method B utilized polyaddn. of a pseudo[2]rotaxane monomer to facilitate the control of the structure, i.e. the rotaxanation ratio. |
DOI | 10.1039/C4CC06943A |
ISSN | 1359-7345 |