研究者情報 | 神奈川大学

チカライシ　ノリコ Chikaraishi Noriko 力石　紀子所属神奈川大学理学部理学科職種助教
言語種別	英語
発行・発表の年月	2018/09
形態種別	学術雑誌
査読	査読あり
標題	Syntheses, structures and antimicrobial activities of gold(I)- and copper(I)-N-heterocyclic carbene (NHC) complexes derived from basket-shaped dinuclear Ag(I)-NHC compex
執筆形態	共著
掲載誌名	Inorganic Chemistry
掲載区分	国外
出版社・発行元	ACS publications
巻・号・頁	57,pp.11322-11332
担当範囲	manuscript praparation
著者・共著者	◎Kenji Nomiya, Soichiro Morozumi, Yuki Yanagawa, Misa Hasegawa, Kaori Kurose, Kenshiro Taguchi,Ryosuke Sakamoto, Kohei Mihara, and Noriko Chikaraishi Kasuga
概要	Novel dinuclear gold(I)- and copper(I)-N-heterocyclic carbene (NHC, L-1a) complexes [M2(L-1a)](PF6)2 (M = AuI (Au-1·PF6) and M = CuI (Cu-1·PF6)) were synthesized by transmetalation of the dinuclear silver(I)−NHC complex [Ag2(L-1a)](PF6)2 (Ag-1·PF6) with [AuCl(Me2S)] or CuI in over 70% yield. The antimicrobial spectra of the three compounds were metal-dependent, and Au-1·PF6 showed the greatest activity toward Gram-positive bacteria.