研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	日本語
発行・発表の年月	2001/03
形態種別	学術雑誌
査読	査読あり
招待論文	招待あり
標題	水素結合を利用したインターロックト分子の高効率合成：ロタキサン、カテナン合成の最近の進歩
執筆形態	共著
掲載誌名	有機合成化学協会誌
巻・号・頁	59(3),206-218頁
著者・共著者	木原　伸浩、高田　十志和
概要	A review with 94 refs. This review summarizes the efficient synthesis of interlocked compds. based on hydrogen-bonding interaction. Various synthetic methods including threading followed by end-capping, clipping, slipping, entering, and polyslipping are discussed. Synthesis under thermodn. control is also discussed. Various amide-based catenanes and rotaxanes have been synthesized using the template effect based on amide-amide H bonding or anion recognition by macrolactam. The strong H bonding between cucurbituril and ammonium salts allowed to prep. various structures of catenanes, rotaxanes, and polyrotaxanes. Further, secondary ammonium salts can be captured into the rings of crown ethers consisting ≥24 ring member to give pseudorotaxanes. A wide variety of end-capping techniques have been developed to give crown ether-based rotaxanes. Control of intramol. H bonding interaction in the interlocked compds. are briefly discussed.
DOI	10.5059/yukigoseikyokaishi.59.206
ISSN	0037-9980