研究者情報 | 神奈川大学

イワクラ　イズミ Iwakura Izumi 岩倉　いずみ所属神奈川大学化学生命学部応用化学科神奈川大学大学院工学研究科工学専攻（応用化学領域）職種教授
言語種別	英語
発行・発表の年月	2006/11
形態種別	学術雑誌
査読	査読あり
標題	The Reactive Intermediate of Catalytic Borohydride Reduction by Schiff-base Cobalt Complexes.
執筆形態	共著
掲載誌名	Chemistry an Asian Jounal,
掲載区分	国外
巻・号・頁	1(5),pp.656-663
担当区分	筆頭著者
著者・共著者	◎Izumi Iwakura, Miho Hatanaka, Ai Kokura, Haruna Teraoka, Taketo Ikeno, Takushi Nagata, Tohru Yamada
概要	The key reactive intermediate of borohydride reduction catalyzed by Schiff base-cobalt complexes is proposed to be the dichloromethylcobalt hydride with a sodium cation, based on experimental and theoretical studies. It was revealed that chloroform is not the solvent but the reactant that activates the cobalt catalyst. The substrate carbonyl compounds are fixed and activated by the alkali cation, which is captured by the oxygen atoms of the planar ligand and the chlorine atom of the axial ligand, and attacked by the hydride on the cobalt atom via a six-membered-like transition state to afford the corresponding alcohol.
DOI	https://doi.org/10.1002/asia.200600150
researchmap用URL	https://onlinelibrary.wiley.com/doi/10.1002/asia.200600150