研究者情報 | 神奈川大学

イワクラ　イズミ Iwakura Izumi 岩倉　いずみ所属神奈川大学化学生命学部応用化学科神奈川大学大学院工学研究科工学専攻（応用化学領域）職種教授
言語種別	英語
発行・発表の年月	2008/05
形態種別	学術雑誌
査読	査読あり
標題	Observation of transition state in Raman triggered oxidation of chloroform in the ground state by real-time vibrational spectroscopy.
執筆形態	共著
掲載誌名	Chemical Physics Letters,
掲載区分	国外
出版社・発行元	ELSEVIER
巻・号・頁	457(4-6),pp.421-426
担当区分	筆頭著者
国際共著	国際共著
著者・共著者	◎Izumi Iwakura, Atsushi Yabushita, Takayoshi Kobayashi
概要	A transition state (TS) during Raman triggered oxidation of chloroform was directly observed by ultrafast spectroscopy using broadband visible sub-5 fs pulses. Changes in the molecular structures including the TSs along the reaction pathways were detected by the time-dependent instantaneous frequencies of vibrational modes. The Raman triggered oxidation of chloroform was found to be initiated by the excitation of vibrational levels through stimulated Raman processes involving the ground-state chloroform-oxygen complex.
DOI	https://doi.org/10.1016/j.cplett.2008.03.003
researchmap用URL	https://www.sciencedirect.com/science/article/pii/S0009261408003357