研究者情報 | 神奈川大学

イワクラ　イズミ Iwakura Izumi 岩倉　いずみ所属神奈川大学化学生命学部応用化学科神奈川大学大学院工学研究科工学専攻（応用化学領域）職種教授
言語種別	英語
発行・発表の年月	2008/10
形態種別	学術雑誌
査読	査読あり
標題	Ultrafast Vibronic Process of Ru Porphyrin Complex.
執筆形態	共著
掲載誌名	European Journal of Inorganic Chemistry
掲載区分	国外
巻・号・頁	2008(31),pp.4856-4860
担当区分	筆頭著者
国際共著	国際共著
著者・共著者	◎Izumi Iwakura, Atsushi Yabushita, Takayoshi Kobayashi
概要	The excited-state dynamics of Ru^II(TPP)(CO)(acetone) was investigated by using a sub-5- fs pulse. In previous studies, the fluorescence lifetime of Ru^II(TPP)(CO) could not be resolved and was reported to be 1 ps. Analysis of the six-coordinate complexes of Ru^II(TPP)(CO)(acetone) showed that ¹Qx(π,π^) had a lifetime of 140 fs and the lifetime of ³(d,π^) was 560 fs. Stimulated emission due to a spin-forbidden transition from ³(π,π^*) to the ground state was observed for the first time.
DOI	https://doi.org/10.1002/ejic.200800532
researchmap用URL	https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.200800532