研究者情報 | 神奈川大学

ホリ　ヒサオ Hori Hisao 堀　久男所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2021/02
形態種別	学術雑誌
査読	査読あり
標題	Efficient mineralization of a novel fluorotelomer surfactant, 2H,3H,3H,5H,5H,6H,6H-4-thia-perfluoro(2-methyl)-1-dodecanoic acid, in superheated water induced by a combination of potassium permanganate and dioxygen
執筆形態	共著
掲載誌名	Chemical Engineering Journal
掲載区分	国外
出版社・発行元	Elsevier
巻・号・頁	405,pp.127006
著者・共著者	Hisao Hori ^a,*, Tomoki Ushio ^a, Takuma Asai ^a, Ryo Honma ^a, Nadim Eid ^b, Bruno Ameduri ^b a Department of Chemistry, Faculty of Science, Kanagawa University, 2946 Tsuchiya, Hiratsuka 259-1293, Japan b Institut Charles Gerhardt, Univ Montpellier, CNRS, ENSCM, Montpellier, France
概要	Mineralization of a fluorotelomer surfactant containing a C6F13 end-group (FSC), in hot and superheated water was studied. Treatment of FSC with a combination of KMnO4 and O2 efficiently decomposed the surfactant to F−, SO42−, and CO2. Specifically, when aqueous FSC (34.8 μmol) and KMnO4 (0.50 mmol) were reacted at 350 °C for 18 h under O2 (13.6 mmol), the F−, CO2, and SO42− yields reached 82, 84, and 97%, respectively, that is, most of fluorine, carbon, and sulfur atoms were mineralized.
DOI	10.1016/j.cej.2020.127006