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ホリ ヒサオ
Hori Hisao 堀 久男 所属 神奈川大学 理学部 理学科 神奈川大学大学院 理学研究科 理学専攻（化学領域） 職種 教授 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2025/08 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | Subcritical Water-Driven Complete Mineralization of Silane Coupling Agents with Short Perfluoroalkyl Chains |
| 執筆形態 | 共著 |
| 掲載誌名 | ACS Omega |
| 掲載区分 | 国外 |
| 出版社・発行元 | American Chemical Society |
| 巻・号・頁 | 10(31),pp.35086-35094 |
| 担当区分 | 筆頭著者,最終著者,責任著者 |
| 著者・共著者 | Hisao Hori, Hiroto Hanashima, Hisashi Saito |
| 概要 | The decomposition of CF3CH2CH2Si(OMe)3 and C4F9CH2CH2Si(OMe)3, typical fluorinated silane coupling agents used for surface modification, was investigated in subcritical water for potential waste treatment applications. When CF3CH2CH2Si(OMe)3 was heated in subcritical water with no additive at 350 degrees, only a small amount of fluoride was produced. In contrast, virtually complete mineralization of CF3CH2CH2Si(OMe)3 was achieved in the presence of KMnO4. Furthermore, under the same reaction conditions, quasi-complete mineralization of C4F9CH2CH2Si(OMe)3 was also attained. |
| DOI | 10.1021/acsomega.5c04738 |
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