研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	1993/08
形態種別	学術雑誌
査読	査読あり
標題	Synthesis and Properties of Poly(hydroxyurethane)s
執筆形態	共著
掲載誌名	J. Polym. Sci. Part A: Polym. Chem.
巻・号・頁	31(12),pp.2765-2773
著者・共著者	Nobuhiro Kihara and Takeshi Endo
概要	Polyaddn. of bis(cyclic carbonate)s and hexamethylenediamine (I) or dodecamethylenediamine in DMSO or DMAc afforded corresponding poly(hydroxyurethane)s (PHU). The presence of H2O, MeOH, or EtOAc in the solvent had little effect on the Mn of the polymer obtained. Polyaddn. of bis(cyclic carbonate) bearing ester groups and I also afforded the corresponding PHU without aminolysis of the ester groups. PHU easily undertook crosslinking at room temp. by the treatment with diisocyanate or (iso-OPr)3Al. The gel crosslinked by (iso-OPr)3Al regenerated the original polymer at room temp. by treatment with HCl.
DOI	10.1002/pola.1993.080311113
ISSN	0887-624X