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イワクラ イズミ
Iwakura Izumi 岩倉 いずみ 所属 神奈川大学 化学生命学部 応用化学科 神奈川大学大学院 工学研究科 工学専攻（応用化学領域） 職種 教授 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2010/07 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | Solvent effect for ruthenium porphyrin. |
| 執筆形態 | 共著 |
| 掲載誌名 | Science China Physics, Mechanics & Astronomy |
| 掲載区分 | 国外 |
| 巻・号・頁 | 53(6),pp.1005-1012 |
| 担当区分 | 筆頭著者 |
| 国際共著 | 国際共著 |
| 著者・共著者 | ◎Izumi Iwakura, Atsushi Yabushita, Takayoshi Kobayashi |
| 概要 | Relaxation of electronic excited-state and vibrational dynamics in the electronic excited state in RuII(TPP)(CO) [TPP=tetraphenylporphyrin] dissolved in N2 bubbled benzene, O2 bubbled benzene, N2 bubbled chloroform and N2 bubbled acetone were clarified using a sub-5fs laser pulse. The result showed that the transition energy from the 1Qx states, consisting of the 1Qx(1,0)(π,π*) state (existing at 18800 cm-1) and 1Qx(0,0)(π,π*) state (existing at 17800 cm-1), to the 1M state of six-coordinated ruthenium complex is lower than that of the five-coordinated ruthenium complex. The intersystem crossing 1Qx(0,0)(π,π*)->3(d,π*) in the five-coordinate RuII(TPP)(CO) in the solution was found to take place in about 1 ps. |
| researchmap用URL | https://link.springer.com/article/10.1007/s11433-010-3212-1 |
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