研究者情報 | 神奈川大学

イワクラ　イズミ Iwakura Izumi 岩倉　いずみ所属神奈川大学化学生命学部応用化学科神奈川大学大学院工学研究科工学専攻（応用化学領域）職種教授
言語種別	英語
発行・発表の年月	2011/01
形態種別	学術雑誌
査読	査読あり
標題	Non-thermal reaction triggered by a stimulated Raman process using 5-fs laser pulses in the electronic ground state: Claisen rearrangement of allyl phenyl ether.
執筆形態	共著
掲載誌名	Chemical Physics Letters
掲載区分	国外
出版社・発行元	ELSEVIER
巻・号・頁	501(4-6),pp.567-571
担当区分	筆頭著者,責任著者
国際共著	国際共著
著者・共著者	◎Izumi Iwakura*, Atsushi Yabushita, Takayoshi Kobayashi
概要	The vibrational populations of allyl phenyl ether were excited by a broadband visible 5-fs laser pulse by the stimulated Raman process to promote a "non-thermal" Claisen rearrangement reaction in the electronic ground state. Analyses of the time-resolved vibrational spectra observed in the subpicosecond region has shown that the Claisen rearrangement proceeds in the following three-step pathway: (1) weakening of the C³O bond to generate a bis-allyl intermediate, (2) formation of the weak C¹C⁵ bond results in the generation of a six-membered structure, and (3) simultaneous processes of C³O breaking and C¹C⁵formation leading to the generation of a keto-intermediate.
DOI	https://doi.org/10.1016/j.cplett.2010.11.028
researchmap用URL	https://www.sciencedirect.com/science/article/pii/S0009261410014946