研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	1994/10
形態種別	学術雑誌
査読	査読あり
標題	Self-Catalyzed Carbon Dioxide-Incorporation System. The Reaction of Copolymer Bearing Oxirane and Quarternary Ammonium Group and Carbon Dioxide
執筆形態	共著
掲載誌名	Macromolecules
巻・号・頁	27(22),pp.6239-6244
著者・共著者	Nobuhiro Kihara and Takeshi Endo
概要	Copolymers of glycidyl methacrylate (GMA) and N-benzyl-N-[2-(methacryloyloxy)ethyl]-N,N-dimethylammonium bromide (I) were synthesized by radical copolymn. in MeCN using AIBN as an initiator. When the copolymers were reacted with CO2 at 100-130 °, 75-86% of the epoxide groups were converted to the five-membered cyclic carbonate moiety by self-catalyzation. A crosslinked copolymer was synthesized by radical copolymn. of GMA, I, and divinylbenzene (93:5:2) and exposed to CO2 to attain 61% incorporation at 140 ° for 500 min.
DOI	10.1021/ma00100a002
ISSN	0024-9297