研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2000/03
形態種別	学術雑誌
査読	査読あり
標題	Reaction of Various Oxiranes and Carbon Dioxide. Synthesis and Aminolysis of Five-Membered Cyclic Carbonates
執筆形態	共著
掲載誌名	Bull. Chem. Soc. Jpn.
巻・号・頁	73(3),pp.713-719
著者・共著者	Takeshhi Iwasaki, Nobuhiro Kihara, and Takeshi Endo
概要	Various oxiranes reacted with carbon dioxide at 100 °C using lithium bromide as a catalyst under atm. pressure to afford the corresponding five-membered cyclic carbonates quant. The rate of the reaction increased as the bulkiness of substituents on the oxirane ring was reduced or an electron-withdrawing group was introduced on the oxirane ring. The stereochem. of the reaction of oxirane and carbon dioxide was retention without loss of optical purity. When substituted phenylethylene carbonates were reacted with benzylamine, the selectivity to afford secondary alc. increased as the electron-withdrawing ability of the para-substituent increased.
DOI	10.1246/bcsj.73.713
ISSN	0009-2673