研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2002/09
形態種別	学術雑誌
査読	査読あり
標題	Tributylphosphine-catalyzed Acylation of Alcohol by Active Ester Directed toward Effective End-capping of Pseudorotaxane Consisting of Ammonium Group and Crown Ether
執筆形態	共著
掲載誌名	Chem. Lett.
巻・号・頁	(9),pp.924-925
著者・共著者	Nobuhiro Kihara, Naohisa Nakakoji, and Toshikazu Takata
概要	According to the results of a model study using benzyl alc., pseudorotaxane with a terminal hydroxy group on the axle was acylated with S-2-pyridyl 3,5-dimethylthiobenzoate in the presence of tributylphosphine to produce rotaxane in 85% yield. Optically active [2]rotaxane and [3]rotaxane were readily synthesized by this method.
DOI	10.1246/cl.2002.924
ISSN	0366-7022