研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2004/05
形態種別	学術雑誌
査読	査読あり
標題	Redox Behavior of Ferrocene-Containing Rotaxane: Transposition of the Rotaxane Wheel by Redox Reaction of a Ferrocene Moiety Tethered at the End of the Axle
執筆形態	共著
掲載誌名	Org. Lett.
巻・号・頁	6(11),pp.1693-1696
著者・共著者	Nobuhiro Kihara, Makiko Hashimoto, and Toshikazu Takata
概要	A rotaxane with a ferrocene moiety at the axle terminus was prepared. The redox potential of the ferrocene moiety decreased by ca. 80 mV when the rotaxane had a crown ether wheel capable of moving on the axle. Thus, the stabilization of the oxidized state of the ferrocene moiety is assumed to accompany the transposition of the wheel component on the axle toward the ferrocene moiety.
DOI	10.1021/ol049817d
ISSN	1523-7060