研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2004/11
形態種別	学術雑誌
査読	査読あり
標題	Is the tert-Butyl Group Bulky Enough to End-Cap a Pseudorotaxane with a 24-Crown-8-ether Wheel?
執筆形態	共著
掲載誌名	Org. Lett.
巻・号・頁	6(24),pp.4507-4509
著者・共著者	Yuya Tachibana, Nobuhiro Kihara, Yoshio Furusho, and Toshikazu Takata
概要	Although rotaxane chemists have long believed that the tert-butyl group is bulkier than the cavity of dibenzo-24-crown-8-ether (DB24C8), it is essentially smaller than the cavity of DB24C8. The tert-butyl (or 4-tert-butylphenyl) group can actually function as an end-cap of DB24C8-based rotaxanes when the intercomponent interaction is effectively operative. When such attractive interaction is removed, deslippage occurs.
DOI	10.1021/ol048135n
ISSN	1523-7060