イワクラ イズミ   Iwakura Izumi
  岩倉 いずみ
   所属   神奈川大学  工学部 化学教室
    神奈川大学大学院  工学研究科 工学専攻(応用化学領域)
   職種   教授
言語種別 英語
発行・発表の年月 2017/08
形態種別 学術雑誌
査読 査読あり
標題 Real-time observation of interfragment vibration and charge transfer within the TCNQF4 dimer
執筆形態 共著
掲載誌名 Chemical Physics
掲載区分国外
出版社・発行元 Elsevier
巻・号・頁 493,pp.56-60
著者・共著者 Sena Hashimoto, Atsushi Yabushita, Izumi Iwakura*
概要 The organic electron acceptors, TCNQ and TCNQF4, are widely used to synthesize multivalent CT complexes. Their corresponding radical anion complexes have specific electronic, optical, and magnetic characters that have attracted attention in the field of materials development. In the present work, we have performed time-resolved absorption spectroscopy of the (Na+)2(TCNQF4rad -)2 to elucidate the reaction dynamics ([TCNQF4rad -]2 -> TCNQF4 + TCNQF42-). A visible sub-10 fs laser pulse was used to observe the ultrafast dynamics of the charge transfer and real-time change of the molecular structure during the reaction.