研究者情報 | 神奈川大学

イワクラ　イズミ Iwakura Izumi 岩倉　いずみ所属神奈川大学化学生命学部応用化学科神奈川大学大学院工学研究科工学専攻（応用化学領域）職種教授
言語種別	英語
発行・発表の年月	2021/07
形態種別	学術雑誌
査読	査読あり
標題	Crystallization of Highly Soluble Thioglucopyranoside Ejected by Coherent Molecular Vibrational Excitation using a Visible 10-fs Pulsed Laser.
執筆形態	共著
掲載誌名	New Journal of Chemistry
掲載区分	国外
出版社・発行元	RSC
巻・号・頁	45(28),pp.12346-12350
担当区分	筆頭著者,責任著者
著者・共著者	◎ Izumi Iwakura*, Sena Hashimoto, Kotaro Okamura, Keiko Komori-Orisaku, Shoji Akai and Atsushi Yabushita
概要	Under irradiation with a visible 10 fs pulsed laser, crystals can be formed by ejection from the solution phase to the gas phase due to coherent molecular vibrational excitation. Crystallization resulting from ejection by coherent molecular vibration was previously demonstrated for a glucopyranoside containing a hydrophobic substituent exhibiting poor solubility in methanol. The present work has further improved the experimental conditions to demonstrate crystallization of a glucopyranoside with a hydrophilic substituent that is highly soluble in methanol. Solvent effects on the crystallizations of the two glucopyranosides ejected by coherent molecular vibrational excitation were compared, and they showed that the solvent parameters for the crystallizations included not only the ejection induced under coherent excitation of Raman-active molecular vibrations but also the solubility of the solute in the solvent used.
DOI	https://doi.org/10.1039/D1NJ01429C
researchmap用URL	https://pubs.rsc.org/en/Content/ArticleLanding/2021/NJ/D1NJ01429C#!divAbstract