イワクラ イズミ   Iwakura Izumi
  岩倉 いずみ
   所属   神奈川大学  化学生命学部 応用化学科
    神奈川大学大学院  工学研究科 工学専攻(応用化学領域)
   職種   教授
言語種別 英語
発行・発表の年月 2008/05
形態種別 学術雑誌
査読 査読あり
標題 Observation of transition state in Raman triggered oxidation of chloroform in the ground state by real-time vibrational spectroscopy.
執筆形態 共著
掲載誌名 Chemical Physics Letters,
掲載区分国外
出版社・発行元 ELSEVIER
巻・号・頁 457(4-6),pp.421-426
担当区分 筆頭著者
国際共著 国際共著
著者・共著者 ◎Izumi Iwakura, Atsushi Yabushita, Takayoshi Kobayashi
概要 A transition state (TS) during Raman triggered oxidation of chloroform was directly observed by ultrafast spectroscopy using broadband visible sub-5 fs pulses. Changes in the molecular structures including the TSs along the reaction pathways were detected by the time-dependent instantaneous frequencies of vibrational modes. The Raman triggered oxidation of chloroform was found to be initiated by the excitation of vibrational levels through stimulated Raman processes involving the ground-state chloroform-oxygen complex.
DOI https://doi.org/10.1016/j.cplett.2008.03.003
researchmap用URL https://www.sciencedirect.com/science/article/pii/S0009261408003357