イケハラ タカユキ   Ikehara Takayuki
  池原 飛之
   所属   神奈川大学  化学生命学部 応用化学科
    神奈川大学大学院  工学研究科 工学専攻(応用化学領域)
   職種   教授
言語種別 日本語
発行・発表の年月 2013/03
形態種別 学術雑誌
査読 査読あり
標題 Relation between the helical twist and S-shaped cross section of the lamellar crystals of polyethylene
執筆形態 共著
掲載誌名 Scientific Reports
巻・号・頁 3,1444; DOI:10.1038/srep01444頁
著者・共著者 Takayuki Ikehara and Toshiyuki Kataoka
概要 The relation between the handedness of helical twist and the S-shaped cross section of the lamellar crystals is discussed for linear polyethylene. The lamellar crystals are found to rotate so that the convex surfaces of ``S'' push aside the melt when they advance in the growth direction. This relation, which has not been examined sufficiently so far, is found to be opposite from what was proposed earlier. Amodel to explain these observations is presented. This paper also demonstrates that the twist handedness can be clarified based on the stack order of crystalline lamellae without any treatment such as etching or extraction to isolate the lamellar crystals.