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イケハラ タカユキ
Ikehara Takayuki 池原 飛之 所属 神奈川大学 化学生命学部 応用化学科 神奈川大学大学院 工学研究科 工学専攻（応用化学領域） 職種 教授 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2019/06 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | Chiral Nucleating Agents Affecting the Handedness of Lamellar Twist in the Banded Spherulites in Poly(ε-Caprolactone)/Poly(Vinyl Butyral) Blends |
| 執筆形態 | 共著 |
| 掲載誌名 | ACS Macro Letters |
| 掲載区分 | 国外 |
| 巻・号・頁 | 8,pp.871-874 |
| 担当範囲 | Resarch design, data analysis, discussion, and writing the paper |
| 著者・共著者 | ◎Takayuki Ikehara, Toshiyuki Kataoka, Manabu Inutsuka, Ren-Hua Jin |
| 概要 | Chiral silica, which acts as a nucleating agent of poly(ε-caprolactone) (PCL), was demonstrated to induce excess handedness of lamellar twist in the banded spherulites of PCL blended with poly(vinyl butyral). The D- and L-forms of silica enhanced the right- and left-handed twists, respectively. The influences of chiral silica on the twist handedness were statistically significant. These results indicate that the handedness
of twisting can be controlled upon primary nucleation. The organic substances used as chiral templates of silica had no effect on the handedness; silica was shown to govern the handedness. The possible mechanisms of the chirality transfer are discussed. |
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