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チカライシ ノリコ
Chikaraishi Noriko 力石 紀子 所属 神奈川大学 理学部 理学科 職種 助教 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2023/05 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | Synthesis and structure of photodegradable 1-(4,5-dimethoxy-2,3-dinitrophenyl)-2-methylpropyl N-butylcarbamate |
| 執筆形態 | 共著 |
| 掲載誌名 | Acta Cryst. |
| 掲載区分 | 国外 |
| 出版社・発行元 | IUCr |
| 巻・号・頁 | E79,pp.549-551 |
| 著者・共著者 | ◎Takafumi Honda, Michiko Ito, Kazuo Yamaguchi, Noriko Chikaraishi Kasuga and Hiroyasu Sato |
| 概要 | The reaction of 1-(4,5-dimethoxy-2,3-dinitrophenyl)-2-methylpropan-1-ol and
butylisocyanate using dibutyltin dilaurate as a catalyst afforded 1-(4,5-dimethoxy- 2,3-dinitrophenyl)-2-methylpropyl N-butylcarbamate, C17H25N3O8, which released butylamine upon photoirradiation. Single crystals of the title compound were grown in a 1:1 mixed solution of hexane and ethyl acetate. Two nitro groups and one methoxy group are twisted out of the plane of the aromatic ring in the novel photo-protecting group. Intermolecular hydrogen bonds are observed between N-butylcarbamate moieties parallel to the a axis. |
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