ホリ ヒサオ   Hori Hisao
  堀 久男
   所属   神奈川大学  理学部 化学科
   職種   教授
言語種別 日本語
発行・発表の年月 2016/06
形態種別 学術雑誌
査読 査読あり
標題 Efficient FeO-induced decomposition of the fluorinated room-temperature ionic liquid [Me3PrN][(CF3SO2)2N] to fluoride ions in subcritical and supercritical water
執筆形態 共著
掲載誌名 Journal of Fluorine Chemistry
掲載区分国外
出版社・発行元 Elsevier
巻・号・頁 186,60-65頁
著者・共著者 Hisao Hori, Akihiro Takahashi, Takaaki Ito
概要 Decomposition of [Me3PrN][(CF3SO2)2N], a typical room-temperature ionic liquid used for electrochemical devices, in subcritical and supercritical water was investigated with the aim of developing a technique to recover the fluorine component from ionic liquid wastes. When the water was heated to the supercritical state with FeO, under which conditions FeO underwent in situ disproportionation to form zerovalent iron and Fe3O4,the substrate effciently decomposed to fluoride ions with a maximum yield of 90 %.
DOI 10.1016/j.jfluchem.2016.04.007