研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2005/05
形態種別	学術雑誌
査読	査読あり
標題	Efficient synthesis of [2]- and higher order rotaxanes via the transition metal-catalyzed hydrosilylation of alkyne
執筆形態	共著
掲載誌名	Tetrahedron Lett.
巻・号・頁	46(22),pp.3851-3853
著者・共著者	Hisahiro Sasabe, Nobuhiro Kihara, Kazuhiko Mizuno, Akiya Ogawa, Toshikazu Takata
概要	A novel end-capping method of pseudorotaxanes via the hydrosilylation of the alkyne of the axle terminal was developed. RuHCl(CO)(PPh3)3 and RhCl(CO)(PPh3)3 complexes catalyzed the hydrosilylation reactions of the alkyne moiety of several pseudorotaxanes at ambient temp. to give the corresponding [2]- and higher order rotaxanes in high yields with excellent regio- and stereoselectivity.
DOI	10.1016/j.tetlet.2005.03.186
ISSN	0040-4039