研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2007/01
形態種別	学術雑誌
査読	査読あり
標題	Catalytic Asymmetric Synthesis and Optical Resolution of Planar Chiral Rotaxane
執筆形態	共著
掲載誌名	Chem. Lett.
巻・号・頁	36(1),pp.162-163
著者・共著者	Yoshimasa Makita, Nobuhiro Kihara, Naohisa Nakakoji, Toshikazu Takata, Shinji Inagaki, Chiyo Yamamoto, Yoshio Okamoto
概要	Planar chiral rotaxanes were synthesized from crown ether and secondary ammonium salt via trialkylphosphine-catalyzed acylative end-capping. Their optical resoln. was achieved by chiral HPLC after acylative neutralization of the ammonium group. When optically active phosphine (Me3CPMeCH2)2 was used as the chiral acylation catalyst, optically active rotaxane (4.4% ee) was obtained.
DOI	10.1246/cl.2007.162
ISSN	0366-7022