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キハラ ノブヒロ
Kihara Nobuhiro 木原 伸浩 所属 神奈川大学 理学部 理学科 神奈川大学大学院 理学研究科 理学専攻（化学領域） 職種 教授 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2019/03 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | Thermally Stable Diels-Alder Polymer Using an Azodicarbonyl Compound as the Dienophile |
| 執筆形態 | 共著 |
| 掲載誌名 | Polymer |
| 掲載区分 | 国外 |
| 出版社・発行元 | Elsevier |
| 巻・号・頁 | 167,pp.60-66 |
| 著者・共著者 | Masayoshi Sakurai, Nobuhiro Kihara |
| 概要 | A novel Diels-Alder polymerization system was developed, using an azodicarbonyl compound as the dienophile. A bis(azodicarbonyl) monomer was prepared by quantitative oxidation of bis(diacylhydrazine) with tBuOCl in the presence of pyridine. Diels-Alder polymerization was carried out with a bisdiene monomer, using AgOTf as the catalyst. High thermal stability of the polymer is characteristic for the products of this Diels-Alder polymerization system, in which the Diels-Alder reaction is irreversible. The C=C bond in the Diels-Alder polymer can be cleaved by ozonolysis to give a polyketone. |
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