研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	1998/08
形態種別	学術雑誌
査読	査読あり
標題	Reaction of Methyl Thioglycolate with Chloromethylstyrene Microgel: Preparation of Core-Shell Type Microgel by Chemical Modification
執筆形態	共著
掲載誌名	J. Appl. Polym. Sci.
巻・号・頁	69(9),pp.1863-1873
著者・共著者	Nobuhiro Kihara, Yukihiro Adachi, Kimitaka Nakao, and Takashi Fukutomi
概要	A uniform spherical poly(chloromethylstyrene) (PCMS) microgel whose av. diam. was 2.3 μm was prepd. by dispersion copolymn. of chloromethylstyrene and divinylbenzene in the presence of poly(vinylpyrrolidinone). When the PCMS microgel was treated with an excess amt. of Me thioglycolate (MTG) in the presence of DBU, sulfenylated microgel was obtained. The introduction ratio of MTG corresponded well to the amt. of DBU used. A transmission electron microscope (TEM) photograph and thermal anal. of the PCMS microgel partially modified by MTG showed that it had a core-shell structure, i.e., an MTG-modified shell and an unchanged core. The PCMS microgel in which 52% of the MTG was introduced was treated with an excess amt. of pyridine in DMAc at 50°C for 48 h followed by acid-catalyzed hydrolysis in dioxane-water at 80°C for 48 h to give a zwitterionic microgel that formed a stable suspension.
DOI	10.1002/(SICI)1097-4628(19980829)69:9<1863::AID-APP22>3.0.CO;2-L
ISSN	0021-8995