研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2000/01
形態種別	学術雑誌
査読	査読あり
標題	"Unlock-Lock" Approach to [2] and [3]Rotaxanes: Entering of a Ring through Disulfide Linkage That is Unlocked by Thiol "Key"
執筆形態	共著
掲載誌名	Chem. Lett.
巻・号・頁	(1),pp.18-19
著者・共著者	Yoshio Furusho, Toshihide Hasegawa, Akiyoshi Tsuboi, Nobuhiro Kihara, and Toshikazu Takata
概要	Both [2] and [3] rotaxanes were prepd. from dibenzo-24-crown-8 and [3,5-(Me3C)2C6H3CH2NHCH2CH2S]2.2HPF6 by treatment with PhSH to cleave the disulfide. During the reversible cleavage of the disulfide linkage, catalyzed by the benzenethiol, the disulfide linkage entered the crown ether to afford the rotaxanes.
DOI	10.1246/cl.2000.18
ISSN	0366-7022